Infrared vibrational spectra of Beta-Phase Mg2SiO4 and Co2SiO4 to Pressures of 27 GPa     

Quentin Williams  Raymond Jeanloz  M. Akaogi 《Physics and Chemistry of Minerals》1986,13(3):141-145

Infrared absorption spectra of the high-pressure polymorphs β-Mg₂SiO₄ and β-Co₂SiO₄ have been measured between 0 and 27 GPa at room temperature. Grüneisen parameters determined for 11 modes of β-Mg₂SiO₄ (frequencies of 300 to 1,050 cm^?1) and 5 modes of β-Co₂SiO₄ (490 to 1,050 cm^?1) range between 0.8 and 1.9. Averaging the mid-infrared spectroscopic data for β-Mg₂SiO₄ yields an average Grüneisen parameter of 1.3 (±0.1), in good agreement with the high-temperature thermodynamic value of 1.35. Similarly, we find a value of 1.05 (±0.2) for the average spectroscopic Grüneisen parameter of β-Co₂SiO₄.  相似文献   

Computation of 5-day temperature normals in western Europe and the Mediterranean area     

Kurt Bender  Ulrich Chorus  Raymond Nybro  Robert Sanderson  Ingrid Weiss 《Pure and Applied Geophysics》1957,38(1):265-285

Summary UsingCraddock's method of representing the annual temperature variation by a two-term harmonic form fitted to monthly means, the harmonic coefficients of 63 stations in western Europe and around the Mediterranean Sea, as well as the 5-day normals for 24 Mediterranean stations, were computed and tabulated. In addition, some of the harmonic coefficients were charted and isoplethed, showing very distinctly the influence of continentality and topography. These charts, together withCraddock's charts for northern and northwestern Europe, provide fairly complete coverage of Europe and the Mediterranean area.This paper was prepared in the offices of the Technical Support Division of the 2d Weather Wing, United States Air Force, as a matter of routine business. The information contained herein was presented at the 5th Meeting of the Italian Society of Geophysics and Meteorology by Dr.Ingrid Weiss (Genoa: 23–25 April 1957). Since the paper is of general interest to all meteorologists of the Mediterranean area, it is published here with the permission of the originating agency as «Mémoire No. 3 du Centre International de Recherches sur la Météorologie de la Méditerranée (CIRMM)».  相似文献   

Multivariate statistical techniques applied to pisolitic laterite geochemistry at Golden Grove, Western Australia     

Raymond E. Smith  N.A. Campbell  R. Litchfield 《Journal of Geochemical Exploration》1984,22(1-3)

Multivariate statistical procedures are applied to pisolitic laterite geochemistry in a study of the Golden Grove massive sulphide district. The objective is to optimize identification of geochemical anomalies caused by base metal mineral deposits.The statistical approach used in this paper depends upon geochemical data for appropriate reference groups (or training sets) being available. The target group consists of orientation data from pisolitic laterite about the Gossan Hill Cu-Zn massive sulphide deposit. A group representing background sequence was selected by combining three subareas in a geochemically quiet part of the prospective acid volcano-sedimentary sequence.A multi-element allocation procedure was set up using data from the reference groups. The exploration samples are then allocated, one sample at a time, to either one of the reference group categories, using the probability of group membership. A map showing the relative probability values for each sample site is the final product for interpretation, aided by ancillary use of an index of typicality.The allocation procedures were carried out using different element combinations, these being based on a procedure for subset selection to give maximum separation of reference groups, and on geochemical insight. Whilst many versions of the allocation procedure gave positive identification of the anomaly related to the blind Scuddles Cu-Zn deposit, allocation using only Cu, Pb, Zn and Ag did not. The results emphasize the importance of pathfinder elements in geochemical studies in weathered terrain.The allocation procedure using the most appropriate element combinations provided more positive identification of the main areas of known mineralization than had the previously used empirically derived methods of Smith and Perdrix (1983). The formal allocation procedure has the following additional advantages: results are not markedly affected by a very high value for any single element since robust procedures are incorporated into the analysis; better discrimination appears to be possible for weaker anomalies; separation of target from background can be optimized by formal calculations instead of by trial and error; and better suppression of background variation results.  相似文献   

Infrared spectra of olivine polymorphs: α, β phase and spinel     

Raymond Jeanloz 《Physics and Chemistry of Minerals》1980,5(4):327-341

Infrared (IR) absorption spectra are presented for olivine (α) and spinel (γ) phases of A₂SiO₄ (A=Fe, Ni, Co) and Mg₂GeO₄. IR spectra of β phase (“modified spinel”) Co₂SiO₄ and of α Mg₂SiO₄ are also included. These results provide reference spectra for the identification of olivine high-pressure polymorphs. Isostructural and isochemical correlations are used to support a general interpretation of the spectra and to predict the spectrum of γ Mg₂SiO₄. A γ Mg₂GeO₄ sample equilibrated at 1,000° C shows evidence of partial inversion, but one equilibrated at 730° C does not. This suggests that partial inversion could occur in silicate spinels at elevated temperatures and pressures, however no evidence of inversion is seen in the ir spectra of the silicates in this study.  相似文献   

Aeolian processes on Venus     

Greeley  Ronald  Arvidson  Raymond E. 《Earth, Moon, and Planets》1990,(1):127-157

In this pre-Magellan review of aeolian processes on Venus we show that the average rate of resurfacing is less than 2 to 4 km/Ga, based on the impact crater size frequency distribution derived from Venera observations, reasonable values of the impact flux, and the assumption of steady state conditions between crater production and obliteration. Viscous relaxation of crater topography, burial by volcanic deposits, tectonic disruption, chemical and mechanical weathering and erosion, and accumulation of windblown sediments probably all contribute to resurfacing. Based on the rate of disappearance of radar-bright haloes around impact craters, the rate of removal of blocky surfaces has been estimated to be about 10^–2 km/Ga. Pioneer-Venus altimetry data show that the average relative permittivity (at 17 cm radar wavelength) of the surface is too high for exposure of soils 10 cm deep, except for ~5% of the planet located primarily in tessarae terrains. The tectonically disrupted tessarae terrains may be sites of soil generation caused by tectonic disruption of bedrock and the presence of relatively steep slopes, or they may be terrains that serve as traps for windblown material. The overall impression is that Venus is a geologically active planet, but one dominated by volcanism and tectonism. On the other hand, theoretical considerations and experimental data on weathering and transport of surface materials suggest rather different conditions. Thermochemical arguments have been advanced that show: (1) CO₂ and SO₂ incorporate into weathering products at high elevation, (2) transport of weathered material by the wind to lower-elevation plains, and (3) re-equilibration of weathered material, releasing both CO₂ and SO₂. In addition, kinetic data suggest a rate of anhydrite formation of 1 km/Ga, a value comparable to the soil erosion rate on Mars, a planet with an active aeolian environment. Experiments and theoretical studies of aeolian processes show that measured surface winds are capable of moving sand and silt on Venus. Assuming that there is a ready sand supply, the flux could be as high as 2.5 × 10^–5 g/cm/s, a value comparable to desert terrains on Earth. In an active aeolian abrasion environment, sand grains could have lifetimes <10³ years. In addition, comminuted debris may be cold-welded to surfaces at the same time as abrasion is occurring. Magellan altimetry and SAR observations should allow assessment of which model for venusian surface modification (active vs. inactive surficial processes) is correct, given the global coverage, high spatial resolution, the calibrated nature of the data, and the potential during extended missions of acquiring multiple SAR views of the surface.Geology and Tectonics of Venus, special issue edited by Alexander T. Basilevsky (USSR Acad. of Sci. Moscow), James W. Head (Brown University, Providence), Gordon H. Pettengill (MIT, Cambridge, Massachusetts) and R. S. Saunders (J.P.L., Pasadena).  相似文献   

Ocean-atmosphere CO2 exchange: An accessible lab simulation for considering biological effects     

David A. Noever  Helen C. Matsos  Raymond J. Cronise  Loren L. Looger  Rachna A. Relwani  Vladimir I. Nikora 《Climatic change》1994,27(3):299-320

Phytoplankton is considered a key component mediating the ocean-atmospheric exchange of carbon dioxide and oxygen. Lab simulations which model biological responses to atmospheric change are difficult to translate into natural settings owing in part to the vertical migration of phytoplankton. In the sea this vertical migration acts to regulate actual carbon dioxide consumption. To capture some critical properties of this vertical material transfer, we monitored the effects of atmospheric CO₂ on dense suspensions of bioconvecting microorganisms. Bioconvection refers to the spontaneous patterns of circulation which arise among such upwardly swimming cells as alga, protozoa, zoospore and large bacteria. Gravity, phototaxis and chemotaxis have all been implicated as affecting pattern-forming ability. The ability of a biologically active suspension to detect atmospheric changes offers a unique method to quantify organism adjustment and vertical migration. With increasing CO₂, bioconvection patterns in alga (P. parva) and protozoa (T. pyriformis) lose their robustness, and surface cell populations retreat from the highest CO₂ regions. Cell movement (both percent motile and mean velocity) generally diminishes. A general program of image analysis yields statistically significant variations in macroscopic migration patterns; both fractal dimension and various crystallographic parameters correlate strongly with carbon dioxide content.  相似文献   

Implications of CO2 global warming on great lakes ice cover     

Raymond A. Assel 《Climatic change》1991,18(4):377-395

Statistical ice cover models were used to project daily mean basin ice cover and annual ice cover duration for Lakes Superior and Erie. Models were applied to a 1951–80 base period and to three 30-year steady double carbon dioxide (2 × CO₂) scenarios produced by the Geophysical Fluid Dynamics Laboratory (GFDL), the Goddard Institute of Space Studies (GISS), and the Oregon State University (OSU) general circulation models. Ice cover estimates were made for the West, Central, and East Basins of Lake Erie and for the West, East, and Whitefish Bay Basins of Lake Superior. Average ice cover duration for the 1951– 80 base period ranged from 13 to 16 weeks for individual lake basins. Reductions in average ice cover duration under the three 2 × CO₂ scenarios for individual lake basins ranged from 5 to 12 weeks for the OSU scenario, 8 to 13 weeks for the GISS scenario, and 11 to 13 weeks for GFDL scenario. Winters without ice formation become common for Lake Superior under the GFDL scenario and under all three 2 × CO₂ scenarios for the Central and East Basins of Lake Erie. During an average 2 × CO₂ winter, ice cover would be limited to the shallow areas of Lakes Erie and Superior. Because of uncertainties in the ice cover models, the results given here represent only a first approximation and are likely to represent an upper limit of the extent and duration of ice cover under the climate change projected by the three 2 × CO₂scenarios. Notwithstanding these limitations, ice cover projected by the 2 × CO₂ scenarios provides a preliminary assessment of the potential sensitivity of the Great Lakes ice cover to global warming. Potential environmental and socioeconomic impacts of a 2 × CO₂ warming include year-round navigation, change in abundance of some fish species in the Great Lakes, discontinuation or reduction of winter recreational activities, and an increase in winter lake evaporation.  相似文献   

Mapping of benthic enrichment patterns in Narragansett Bay,Rhode Island     

Raymond M. Valente  Donald C. Rhoads  Joseph D. Germano  Victor J. Cabelli 《Estuaries and Coasts》1992,15(1):1-17

A synoptic reconnaissance survey was performed over a five-day period in August 1988 to assess benthic habitat quality throughout Narragansett Bay, Rhode Island, using REMOTS^® sediment-profile photography and analysis in combination with measurements of the levels ofClostridium perfringens spores (a fecal indicator) in sediments. Three main areas of degraded benthic habitat quality related to either excessive organic enrichment or physical disturbance were identified based solely on the REMOTS^® analysis: the Providence River Reach, Greenwich Bay and its associated coves and harbors, and an area located along the southwest side of Prudence Island. Sediments at many stations in these areas exhibited shallow apparent redox-potential discontinuity (RPD) depths, high apparent oxygen demand, and low-order benthic successional stages. ElevatedClostridium perfringens spore counts in surface sediments were attributed to inputs from wastewater treatment facilities. The highest spore counts occurred at the head of the bay, where wastewater treatment discharges and associated combined sewer overflows are numerous. Using data from the REMOTS^® analysis and the sediment inventory ofC. perfringens spores, a distinction was made between organic enrichment of the bottom from sewage, versus nonsewage enrichment or physical disturbance. The combination of techniques employed in this investigation could be used to design more efficient monitoring programs to assess eutrophication effects in estuaries and determine the effectiveness of regulatory or management initiatives to reduce organic overenrichment of benthic habitats.  相似文献   

On the excitation of short-term variations in the length of the day and polar motion     

Raymond Hide 《Surveys in Geophysics》1985,7(2):163-167

Variations in the distribution of mass within the atmosphere, and changes in the pattern of winds produce fluctuations in all three components of the angular momentum of the atmosphere on time-scales upwards of a few days. It, has been shown that variations in theaxial component of atmospheric angular momentum during the Special Observing Periods in the recent First GARP Global Experiment (FGGE, where GARP is the Global Atmospheric Research Programme) are well correlated with short-term changes in the length of the day. They are consistent with the total angular momentum of the atmosphere and solid Earth being conserved on short timescales (allowing for lunar and solar effects), without requiring significant angular momentum transfer between the Earth's liquid core and solid mantle on timescales of weeks or months. It has also been shown that fluctuations, in the equatorial components of atmospheric angular momentum make a major contribution to the observed wobble of the instantaneous pole of the Earth's rotation with respect to the Earth's crust. A necessary step in the investigation was a re-examination of the underlying theory of non-rigid body rotational dynamics and angular momentum exchange between the atmosphere and solid Earth. Since only viscous or topographic coupling between the atmosphere and solid Earth can transfer angular momentum, no atmospheric flow that everywhere satisfied inviscid equations (including, but not solely, geostrophic flow) could affect the rotation of a spherical solid Earth. New effective angular momentum functions were introduced in order to exploit the available data and allow for rotational and surface loading deformation of the Earth. A theoretical basis has now been established for future routine determinations of atmopheric, angular momentum fluctuations for the purpose of meteorological and geophysical research, including the assessment of the extent to which movements in the solid Earth associated with very large earthquakes contribute to the excitation of the Chandlerian wobble.  相似文献   

Genetic structure of bay anchovy (Anchoa mitchilli) populations in Chesapeake Bay     

Raymond P. Morgan  Bruce M. Baker  James H. Howard 《Estuaries and Coasts》1995,18(3):482-493

To determine the genetic structure of the bay anchovy (Anchoa mitchilli) within Chesapeake Bay, 16 isozyme systems encoding 21 loci for 20 population were examined using horizontal starch gel electrophoresis. Contingency Chisquare analysis revealed significant allelic frequency differences at nine loci (AAT-1, AAT-2, ALD-1, CPK-2, GAP-1, GLY-1, LDH-1, MDH-1, and MDH-2). Two loci, ALD-1 and MDH-1, were responsible for nine of 14 tests not conforming to Hardy-Weinberg expectations, with some of these deviations attributed to possible scoring and/or sampling error. Estimates for mean average heterozygosity were relatively high, ranging from 0.40 to 0.096, with 33–57% of the loci polymorphic. A low F_st value (0.041) along with high genetic identity estimates (I=0.997) indicated little substructuring of bay anchovy populations within Chesapeake Bay.  相似文献